SYNTHESIS AND STRUCTURE OF TRIMETHYLLEAD NIOBOCENE DIHYDRIDE

Authors
NIKONOV GI AVTOMONOV EV MASSA W
Citation
Gi. Nikonov et al., SYNTHESIS AND STRUCTURE OF TRIMETHYLLEAD NIOBOCENE DIHYDRIDE, Chemische Berichte, 130(11), 1997, pp. 1629-1631
Citations number
31
Categorie Soggetti
Chemistry
Journal title
Chemische Berichte → ACNP
ISSN journal
00092940
Volume
130
Issue
11
Year of publication
1997
Pages
1629 - 1631
Database
ISI
SICI code
0009-2940(1997)130:11<1629:SASOTN>2.0.ZU;2-G
Abstract
The reaction of niobocene trihydride [Cp2NbH3] with ClPbMe3 in the pre sence of amine affords the plumbido dihydride complex [Cp(2)NbH2(PbMe3 )] (1). Compound 1 represents the first example of a stable complex wi th neighbouring hydride and terminal plumbyl substituents. The structu re of this compound has been established by NMR and IR spectroscopy an d confirmed by an X-ray structure analysis.