Photoluminescence of excitons and their phonon replicas in homoepitaxi
al MOCVD-grown gallium nitride (GaN) layers have been studied by picos
econd tps) time-resolved photoluminescence spectroscopy. The time-reso
lved photoluminescence spectroscopy has shown that the free excitons a
nd their replicas have the fastest dynamics (decay time of about 100 p
s). Then, the excitons-bound-to-donors emission rises (with the rise t
ime similar to the free excitons decay time) and decays with t = 300 p
s. The excitons-bound-to-acceptors has the slowest decay (about 500 ps
). It has been found that the ratio of excitons-bound-to-acceptors and
excitons-bound-to-donors amplitudes and their decay times are differe
nt for 1-LO replicas and then for zero-phonon lines, whereas the ratio
of amplitudes and the decay time of the 2-LO replicas are similar to
the ones of the zero-phonon lines.