INELASTIC NEUTRON-SCATTERING, INFRARED, AND RAMAN-SPECTROSCOPIC STUDIES OF MG2FEH6 AND MG2FED6

Authors
PARKER SF WILLIAMS KPJ BORTZ M YVON K
Citation
Sf. Parker et al., INELASTIC NEUTRON-SCATTERING, INFRARED, AND RAMAN-SPECTROSCOPIC STUDIES OF MG2FEH6 AND MG2FED6, Inorganic chemistry, 36(23), 1997, pp. 5218-5221
Citations number
16
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganic chemistry → ACNP
ISSN journal
00201669
Volume
36
Issue
23
Year of publication
1997
Pages
5218 - 5221
Database
ISI
SICI code
0020-1669(1997)36:23<5218:INIARS>2.0.ZU;2-0
Abstract
The combination of the three types of vibrational spectroscopy, infrar ed, Raman, and inelastic neutron scattering, has enabled all of the in ternal, and most of the external, modes of Mg2FeH6 and Mg2FeD6 to be o bserved and assigned, as well as some of the modes of Mg2FeD5H. As an aid to the assignment, a reliable, empirical force field has been deve loped. The spectra also show evidence for a dynamic distortion of the hexahydrido complex, an effect that is not observed for the deuterated species.