Ja. Casares et al., P(CH2CH2PY)(N)PH3-N (PY = 2-PYRIDYL N = 1, 2, 3) AS CHELATING AND AS BINUCLEATING LIGANDS FOR PALLADIUM, Inorganic chemistry, 36(23), 1997, pp. 5251-5256
Several neutral palladium(II) complexes of the type [PdRCl(PNn)] with
the ligands P(CH2CH2Py)Ph-2 (PN), P(CH2CH2Py)(2)Ph (PN2), and P(CH2CH2
Py)(3) (PN3) have been prepared by reacting the corresponding phosphin
es with [Pd-2(mu-Cl)(2)R-2(tht)(2)] (R = C6Cl2F3, C6F5; tht = tetrahyd
rothiophene). In all these complexes, the ligands act as bidentate P,N
-chelating ligands. Abstraction of the chloride with AgBF4 leads to th
e formation of the dimeric compounds [Pd2R2(PN2)(2)](BF4)(2) and [Pd2R
2(PN3)(2)](BF4)(2), in which the PNn ligands act as P,N-chelating and
P,N-bridging ligands. The bridges are labile, and exchange experiments
on mixtures of the complexes with different R groups show the equilib
rium in solution between the dimeric ''pure'' complexes and the mixed
complexes [Pd-2(C6F5)(C6Cl2F3)(PNn)(2)](2+). The structure of the comp
lex [Pd-2(C6Cl2F3)(2)(P(CH2CH2Py)(2)Ph)(2)](BF4)(2) has been studied b
y X-ray diffraction.