C. Derouin et al., HYDRODYNAMICS OF RISER UNITS AND THEIR IMPACT ON FCC OPERATION, Industrial & engineering chemistry research, 36(11), 1997, pp. 4504-4515
The hydrodynamic characteristics of the riser of a FCC plant are inves
tigated in a cold pilot plant. The results are checked and completed w
ith measurements made in real operating FCC units. In both cases, trac
ing of the gas, sampling-probes, and gamma-tomography were used, The g
as and solid velocity profiles are described by using a plug-flow mode
l with radial dispersion. The gas velocity profile is formally represe
nted by an Ostwald-de Waele type equation. The axial solid concentrati
on profile is fitted to data obtained in a commercial FCC unit. The ra
dial dispersion coefficient of the gas is directly measured in the pla
nt. The kinetics of the reactions occurring during catalytic cracking
are investigated in a microreactor and are represented by a 19-lump mo
del including deactivation by coking of the catalyst, A combination of
this reaction model with the hydrodynamic model is able to predict wi
th a good precision the yields of the different product; families obta
ined, in an industrial FCC unit. It is checked by comparison with samp
ling data in the plant, and it yields useful information on the influe
nce of riser hydrodynamics on yields and products quality.