SYNTHESIS AND CRYSTAL-STRUCTURES OF TRIS( DIETHYLAMINO)BENZYLPHOSPHONIUM BROMIDES - [(C2H5)(2)N](3)PCH2C6H5-CENTER-DOT-CH3CN AND [(C2H5)(2)N](3)PCH2C6H5+BR-3(-)(BR)

Authors
VOGT H QUASCHNING V ZIEMER B MEISEL M
Citation
H. Vogt et al., SYNTHESIS AND CRYSTAL-STRUCTURES OF TRIS( DIETHYLAMINO)BENZYLPHOSPHONIUM BROMIDES - [(C2H5)(2)N](3)PCH2C6H5-CENTER-DOT-CH3CN AND [(C2H5)(2)N](3)PCH2C6H5+BR-3(-)(BR), Zeitschrift fur Naturforschung. B, A journal of chemical sciences, 52(10), 1997, pp. 1175-1180
Citations number
7
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur Naturforschung. B, A journal of chemical sciences → ACNP
ISSN journal
09320776
Volume
52
Issue
10
Year of publication
1997
Pages
1175 - 1180
Database
ISI
SICI code
0932-0776(1997)52:10<1175:SACOTD>2.0.ZU;2-A
Abstract
Tris(diethylamino)benzylphosphonium bromide, [(C2H5)(2)N](3)PCH2C6H5Br-. CH3CN (1), has been prepared by the reaction of tris(diethylamino )phosphine with benzylbromide in acetonitrile and its structure determ ined. The colorless crystals are monoclinic, space group P2(1)/n, Z = 4, a = 954.5(11), b = 2552(3), c = 1017.9(9) pm, beta = 92.27(8)degree s. The lattic contains Br- anions and [(C2H5)(2)N](3)PCH2C6H5+ cations . [(C2H5)(2)N](3)PCH2C6H5](+) Br-3(-) (2) has been obtained by treatin g compound 1 with equimolar quantities of elemental bromine in acetoni trile solution. The yellow-red crystals of 2 are monoclinic, space gro up P2(1)/n, Z = 4, a = 1065.1(4), b = 1952.9(2), c = 1201.7(2) pm, bet a = 98.18(2)degrees, and comprise [(C2H5)(2)N](3)PCH2C6H5+ cations and linear Br-3(-) anions.