THE ESTERIFICATION OF GIBBERELLINS WITH DIMETHYLFORMAMIDE DIMETHYL ACETAL (DMFDMA)

Citation
Ms. Ali et al., THE ESTERIFICATION OF GIBBERELLINS WITH DIMETHYLFORMAMIDE DIMETHYL ACETAL (DMFDMA), Zeitschrift fur Naturforschung. B, A journal of chemical sciences, 52(10), 1997, pp. 1237-1244
Citations number
10
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
ISSN journal
09320776
Volume
52
Issue
10
Year of publication
1997
Pages
1237 - 1244
Database
ISI
SICI code
0932-0776(1997)52:10<1237:TEOGWD>2.0.ZU;2-F
Abstract
The key step is to prepare rare gibberellins by converting the more re adily available gibberellins (GA(3), GA(4), GA(7) and GA(13)) into the ir methyl eaters. The DMFDMA is employed as an esterifying reagent to avoid the diazomethane due to its toxic, explosive and hazardous natur e. It is observed that DMFDMA apart from esterification can also be us ed as acetylating and epimerizing reagent.