Lithium tetraborate (Li2B4O7) has attracted much attention as a surfac
e acoustic wave substrate for high-frequency use and its excellent non
linear optical properties have been recently found. In the present rep
ort, the main crystalline defects observed by X-ray topography in Li2B
4O7 (110) wafers grown by the Bridgman method and by the Czochralski m
ethod are presented. The main trends observed are a majority of disloc
ations in {112} planes, a minority of dislocations in the {111} planes
, and low-angle grain boundaries in both {111} and {112} planes.