INTRAMOLECULAR 4-CYCLOADDITIONS - A TOTAL SYNTHESIS OF APHANAMOL(3)

Authors
HARMATA M CARTER KW
Citation
M. Harmata et Kw. Carter, INTRAMOLECULAR 4-CYCLOADDITIONS - A TOTAL SYNTHESIS OF APHANAMOL(3), Tetrahedron letters, 38(46), 1997, pp. 7985-7988
Citations number
25
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
38
Issue
46
Year of publication
1997
Pages
7985 - 7988
Database
ISI
SICI code
0040-4039(1997)38:46<7985:I4-ATS>2.0.ZU;2-Y
Abstract
Treatment of the easily prepared allylic alcohol 11 with triflic anhyd ride gives the cycloadduct 12 in 32% yield. Deprotection results in th e formation of racemic aphanamol I. (C) 1997 Elsevier Science Ltd.