A NOVEL AQUEOUS BARBIER-GRIGNARD-TYPE ALLYLATION OF ALDEHYDES IN A MGBICL3 BIMETAL SYSTEM/

Authors
WADA M FUKUMA T MORIOKA M TAKAHASHI T MIYOSHI N
Citation
M. Wada et al., A NOVEL AQUEOUS BARBIER-GRIGNARD-TYPE ALLYLATION OF ALDEHYDES IN A MGBICL3 BIMETAL SYSTEM/, Tetrahedron letters, 38(46), 1997, pp. 8045-8048
Citations number
35
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
38
Issue
46
Year of publication
1997
Pages
8045 - 8048
Database
ISI
SICI code
0040-4039(1997)38:46<8045:ANABAO>2.0.ZU;2-K
Abstract
The allylation of aldehydes with allylic bromides proceeded smoothly i n a Mg/BiCl3 bimetal system even in THF-H2O to afford the correspondin g homoallylic alcohols in good yields. (C) 1997 Elsevier Science Ltd.