APPLICATION OF ANNULAR CENTRIFUGAL CONTACTOR ON SEPARATING INDIUM FROM IRON

Citation
Xz. Zhou et al., APPLICATION OF ANNULAR CENTRIFUGAL CONTACTOR ON SEPARATING INDIUM FROM IRON, Separation science and technology, 32(16), 1997, pp. 2705-2713
Citations number
6
Categorie Soggetti
Engineering, Chemical",Chemistry
ISSN journal
01496395
Volume
32
Issue
16
Year of publication
1997
Pages
2705 - 2713
Database
ISI
SICI code
0149-6395(1997)32:16<2705:AOACCO>2.0.ZU;2-S
Abstract
It is hard to separate indium from iron in sulfuric acid leachate with out reducing Fe3+ to Fe2+ with di(2-ethylhexyl) phosphoric acid (HDEHP ) by the equilibrium extraction process. A nonequilibrium extraction p rocess with annular centrifugal contactors is studied through the extr action kinetics difference between In and Fe. The mass transfer veloci ties of In and Fe were determined. Laboratory- and industry-scale extr action tests with miniature and industry scale annular centrifugal con tactors, respectively, were conducted. The results indicate the mass t ransfer velocity of In is much faster than that of Fe, the contact tim e between the two phases is very short in the contactor, and the In ca n be well separated from Fe in the nonequilibrium extraction process w ith annular centrifugal contactors.