Xz. Zhou et al., APPLICATION OF ANNULAR CENTRIFUGAL CONTACTOR ON SEPARATING INDIUM FROM IRON, Separation science and technology, 32(16), 1997, pp. 2705-2713
It is hard to separate indium from iron in sulfuric acid leachate with
out reducing Fe3+ to Fe2+ with di(2-ethylhexyl) phosphoric acid (HDEHP
) by the equilibrium extraction process. A nonequilibrium extraction p
rocess with annular centrifugal contactors is studied through the extr
action kinetics difference between In and Fe. The mass transfer veloci
ties of In and Fe were determined. Laboratory- and industry-scale extr
action tests with miniature and industry scale annular centrifugal con
tactors, respectively, were conducted. The results indicate the mass t
ransfer velocity of In is much faster than that of Fe, the contact tim
e between the two phases is very short in the contactor, and the In ca
n be well separated from Fe in the nonequilibrium extraction process w
ith annular centrifugal contactors.