GASEOUS PROTONATED NITROSYL FLUORIDE - EXPERIMENTAL AND THEORETICAL CHARACTERIZATION OF 2 DISTINGUISHABLE ISOMERS, HONF+ AND ONFH+, AND EVALUATION OF THE BARRIER FOR THEIR INTERCONVERSION
M. Aschi et al., GASEOUS PROTONATED NITROSYL FLUORIDE - EXPERIMENTAL AND THEORETICAL CHARACTERIZATION OF 2 DISTINGUISHABLE ISOMERS, HONF+ AND ONFH+, AND EVALUATION OF THE BARRIER FOR THEIR INTERCONVERSION, Journal of physical chemistry, 98(10), 1994, pp. 2713-2718
The structure, stability, interconversion, and unimolecular decomposit
ion processes of gaseous protonated nitrosyl fluoride, ONF, have been
investigated by mass-analyzed ion kinetic energy (MIKE) and collisiona
lly activated dissociation (CAD) mass spectrometry, as well as ab init
io GAUSSIAN-1 calculations. Positive evidence has been obtained for th
e existence of two distinct, not easily interconvertible isomers, HO-N
F+, 1, and ON-FH+, 3. These two species are distinguishable by both CA
D and MIKE spectrometry, whose results are consistent with the theoret
ical description of the system. The fluorine-protonated isomer 3 is th
e global minimum on the surface and is more stable than the oxygen-pro
tonated isomer 1 by 70.1 kcal mol(-1). Whereas isomer 3 has a low-ener
gy dissociation channel to produce NO+ and HF, the less stable isomer
1 is trapped in a deep potential well, which prevents both rapid disso
ciation and isomerization to 3. The GAUSSIAN-1 potential energy diagra
m explains the distinctly different shapes of the MIKE peaks and the k
inetic energy releases (KERs) associated with the reaction (ONFH+ -->
NO+ + HF. The loss of HF from 3 gives rise to a narrow peak with a sma
ll KER, while the same reaction from 1 is associated with a dish-toppe
d peak and an exceptionally large KER (E(t1/2) = 2.68 eV).