EFFECT OF ACTIVATION OF OXYGEN BY ELECTRON-CYCLOTRON-RESONANCE PLASMAON THE INCORPORATION OF PB IN THE DEPOSITION OF PB(ZR,TI)O-3 FILMS BYDC MAGNETRON REACTIVE SPUTTERING
St. Kim et al., EFFECT OF ACTIVATION OF OXYGEN BY ELECTRON-CYCLOTRON-RESONANCE PLASMAON THE INCORPORATION OF PB IN THE DEPOSITION OF PB(ZR,TI)O-3 FILMS BYDC MAGNETRON REACTIVE SPUTTERING, JPN J A P 1, 36(9A), 1997, pp. 5663-5669
Pb(Zr,Ti)O-3 films were deposited by DC magnetron reactive sputtering
on Pt/Ti/SiO2/Si and Pt/SiO2/Si substrates. The activation of oxygen b
y electron cyclotron resonance (ECR) plasma facilitated the incorporat
ion of Pb. This enabled the fabrication of Pb(Zr,Ti)O-3 films With sto
ichiometric composition and perovskite structure even at a high Zr/Ti
film concentration ratio and high substrate temperature and on Pt/SiO2
/Si substrates where the pyrochlore second phase was usually observed
when the films were deposited without oxygen activation.