SYNTHESIS AND CHARACTERIZATION OF THE PLATINUM COMPLEXES WITH N,S OR C,N,S LIGANDS DERIVED FROM 2-PHENYLBENZOTHIAZOLINE

Authors
KAWAMOTO T NAGASAWA I KUMA H KUSHI Y
Citation
T. Kawamoto et al., SYNTHESIS AND CHARACTERIZATION OF THE PLATINUM COMPLEXES WITH N,S OR C,N,S LIGANDS DERIVED FROM 2-PHENYLBENZOTHIAZOLINE, Inorganica Chimica Acta, 265(1-2), 1997, pp. 163-167
Citations number
13
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganica Chimica Acta → ACNP
ISSN journal
00201693
Volume
265
Issue
1-2
Year of publication
1997
Pages
163 - 167
Database
ISI
SICI code
0020-1693(1997)265:1-2<163:SACOTP>2.0.ZU;2-I
Abstract
The preparation of the two platinum complexes, the thiolato-bridged te tranuclear [Pt-4 (phbt)(4)] and the neutral dithiolene-like non-innoce nt mononuclear [Pt(ddbt)], is described. [Pt-4(phbt)(4)]. 2CH(2)ClCH(2 )Cl crystallizes in the monoclinic space group P2(1)/n, with a = 19.89 3(5), b = 17.950(7), c = 14.844(4) Angstrom, beta = 93.69(2)degrees, V = 5289(3) Angstrom(3) and Z = 4. [Pt(ddbt)] crystallizes in the monoc linic space group P2(1)/n,with a = 10.789(9), b = 24.56(2), c = 8.64(1 ) Angstrom, beta = 102.69(8)degrees, V = 2232(4) Angstrom(3) and Z = 4 . (C) 1997 Elsevier Science S.A.