U. Kaup et al., DIETHANOLAMINE IN COOLING LUBRICANT CONCE NTRATES - RESULTS OF AN INVESTIGATION PROGRAM IN 1996, Gefahrstoffe, Reinhaltung der Luft, 57(10), 1997, pp. 417-421
In Germany, the use of diethanolamine in water-mixable cooling lubrica
nts was prohibited with the coming into force of TRGS 611 (1993). In t
he beginning, it was very difficult for the manufacturers to adapt to
the new legal situation. In some cases, the limit value of 0.2% of the
cooling lubricant concentrate was clearly exceeded. In 1996, the comp
etent German Berufsgenossenschaften, the Office for Occupational Safet
y of the Land North Rhine-Westphalia and the Berufsgenossenschaftliche
s Institut fur Arbeitssicherheit - BIA joined together in a measuremen
t programme. The latter was aimed to investigate whether cooling lubri
cants available on the market satisfied the legal requirements. 51 sam
ples were analysed. Six of them showed diethanolamine concentrations a
bove the admissible limit, the maximum concentration reaching 0.85%. T
hese quantities could be due to contaminated basic products. The addit
ion of triethanolamine, which may contain diethanolamine, is particula
rly critical. Manufacturers of cooling lubricants are therefore recomm
ended to make sure the utilised triethanolamine is clean.