A MILD DEHYDRAZINATION REACTION OF ARYLHYDRAZINES USING NITRIC-OXIDE IN THE PRESENCE OF OXYGEN

Authors
MATSUYA Y ITOH T NAGATA K OHSAWA A
Citation
Y. Matsuya et al., A MILD DEHYDRAZINATION REACTION OF ARYLHYDRAZINES USING NITRIC-OXIDE IN THE PRESENCE OF OXYGEN, Tetrahedron, 53(46), 1997, pp. 15701-15710
Citations number
35
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron → ACNP
ISSN journal
00404020
Volume
53
Issue
46
Year of publication
1997
Pages
15701 - 15710
Database
ISI
SICI code
0040-4020(1997)53:46<15701:AMDROA>2.0.ZU;2-H
Abstract
A new dehydrazination reaction of arylhydrazines using nitric oxide an d oxygen as a mild nitrosating agent is described. Taking advantage of non-aqueous and non-acidic medium appears to cause this novel selecti vity as a counterpart of the azide synthesis by the conventional metho ds. The generality and reaction mechanism were also investigated. (C) 1997 Elsevier Science Ltd.