PHOTOMETRIC-DETERMINATION OF 3-QUINUCLIDINOL IN 3-QUINUCLIDINYL ESTERS OF SOME SUBSTITUTED HYDROXYACETIC ACIDS

Authors
STANKOV IN LYSENKO VV ZHMUROVA MI FADEEV VN PANKOV DI
Citation
In. Stankov et al., PHOTOMETRIC-DETERMINATION OF 3-QUINUCLIDINOL IN 3-QUINUCLIDINYL ESTERS OF SOME SUBSTITUTED HYDROXYACETIC ACIDS, Journal of analytical chemistry, 52(11), 1997, pp. 1103-1108
Citations number
25
Categorie Soggetti
Chemistry Analytical
Journal title
Journal of analytical chemistry → ACNP
ISSN journal
10619348
Volume
52
Issue
11
Year of publication
1997
Pages
1103 - 1108
Database
ISI
SICI code
1061-9348(1997)52:11<1103:PO3I3E>2.0.ZU;2-E
Abstract
The Interaction of Bromocresol Green (blue) with 3-quinuclidinol and 3 -quinuclidinyl esters of substituted hydroxyacetic acids in organic so lvent was studied. It was shown that, under these conditions, esters p roduce yellowish orange complexes of composition I : 1, regardless of the ratio between the concentrations of reagents, whereas 3-quinuclidi nol can form complexes of composition I : 1 and 2 : 1, and the latter is blue. A procedure for the spectrophotometric determination of 3-qui nuclidinol in 3-quinuclidinyl esters of some substituted hydroxyacetic acids was developed.