COMPLEXES WITH NITROXIDES CONTAINING DIFFERENT SUBSTITUENTS IN THE ALPHA-POSITION TO N-CENTER-DOT-O GROUP - COMPETITION OF BASICITY AND STERICAL AVAILABILITY OF THE DONOR FUNCTIONS OF NITROXIDES IN METAL-COMPLEXES WITH STERICALLY HINDERED IMIDAZOLINES

Authors
OVCHARENKO V KOROBKOV I FOKIN S BURDUKOV A ROMANENKO G IKORSKII V PERVUKHINA N MAZHUKIN D REZNIKOV V
Citation
V. Ovcharenko et al., COMPLEXES WITH NITROXIDES CONTAINING DIFFERENT SUBSTITUENTS IN THE ALPHA-POSITION TO N-CENTER-DOT-O GROUP - COMPETITION OF BASICITY AND STERICAL AVAILABILITY OF THE DONOR FUNCTIONS OF NITROXIDES IN METAL-COMPLEXES WITH STERICALLY HINDERED IMIDAZOLINES, Molecular crystals and liquid crystals science and technology. Section A, Molecular crystals and liquid crystals, 305, 1997, pp. 311-319
Citations number
10
Categorie Soggetti
Crystallography
Journal title
Molecular crystals and liquid crystals science and technology. Section A, Molecular crystals and liquid crystals → ACNP
ISSN journal
1058725X
Volume
305
Year of publication
1997
Pages
311 - 319
Database
ISI
SICI code
1058-725X(1997)305:<311:CWNCDS>2.0.ZU;2-G
Abstract
In the nitroxide molecule, change of the substituent in the alpha-posi tion to the N .-O group affects both the donor properties of this grou p and its steric availability. Metal complexes with three nitroxide pa irs are used to show that the above change of the alpha-substituent in the nitroxide molecule can induce structural transformation of the mo lecular complex itself(and, as a consequence, change its magnetic prop erties), change the magnetic properties of the solid complex, or chang e the chemical behavior of the nitroxide.