Jj. Pan et al., REACTION-KINETICS OF MUONIUM WITH N2O IN THE GAS-PHASE, The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory, 101(45), 1997, pp. 8470-8479
The thermal reaction Mu + N2O has been studied by the muon spin rotati
on (mu SR) technique at temperatures from 303 to 593 K and pressures u
p to 60 atm. The overall reaction rate coefficient depends on the N2O
pressure quadratically in pure N2O and is proportional to both the N2O
partial pressure and the total pressure in mixtures, confirming the t
heoretical prediction of Diau and Lin that the analogous H atom reacti
on proceeds through two channels in this temperature range, forming di
fferent products, MuN(2)O and MuO + N-2. The measured total rate coeff
icients are much larger than those reported by Marshall et al. for H(D
) + N2O, indicating a dramatic kinetic isotope effect, which is mainly
due to the enhanced quantum tunneling of the ultralight Mu atom. Even
at room temperature (and low pressure), k(Mu)/k(H) approximate to 120
, the largest yet seen in comparisons of gas-phase Mu and H reactivity
at such relatively high temperatures. The addition reaction forming M
uN(2)O (and by implication, HN2O) contributes significantly to the tot
al reaction rate at higher pressures but with the thermal rate coeffic
ient remaining in the termolecular regime even at the highest pressure
s measured.