RATE-CONSTANT FOR THE REACTION OF OH RADICALS WITH DICHLOROMETHANE

Authors
VILLENAVE E ORKIN VL HUIE RE KURYLO MJ
Citation
E. Villenave et al., RATE-CONSTANT FOR THE REACTION OF OH RADICALS WITH DICHLOROMETHANE, The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory, 101(45), 1997, pp. 8513-8517
Citations number
31
Categorie Soggetti
Chemistry Physical
Journal title
The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory → ACNP
ISSN journal
10895639
Volume
101
Issue
45
Year of publication
1997
Pages
8513 - 8517
Database
ISI
SICI code
1089-5639(1997)101:45<8513:RFTROO>2.0.ZU;2-3
Abstract
The rate constant for the reaction of CH2Cl2 with OH was measured by t he flash photolysis resonance fluorescence technique over the temperat ure range 277-370 K to give the following Arrhenius expression: k(DCM) = (2.61(-0.34)(+0.37)) x 10(-12) exp{-(944 +/- 29)/T} cm(3) molecule( -1) s(-1), where the uncertainties represent 95% confidence limits ass ociated with the statistical fitting procedure and include the contrib ution for the expanded uncertainties in the individual rate constant. Based on this new value, the results of recent relative studies of the OH reactions with CHCl2-CFCl2, CH2ClBr, CH2Br2, and CH2FCl have been reanalyzed.