Cw. Chung et Hg. Song, STUDY ON FENCE-FREE PLATINUM ETCHING USING CHLORINE-BASED GASES IN INDUCTIVELY-COUPLED PLASMA, Journal of the Electrochemical Society, 144(11), 1997, pp. 294-296
Platinum thin films have been successfully etched without redeposition
of etch products using chlorine-based gases in an inductively coupled
plasma. The redeposited materials formed on the pattern sidewall by u
sing Cl-2/Ar gas combination were analyzed by x-ray photoelectron spec
troscopy and secondary ion mass spectrometry. We found that the redepo
sited material was mainly PtCl2 compound. Based on this result, SiCl4/
Cl-2/Ar gas chemistry has been proposed as a new etching gas and demon
strated good etching profile of Pt films without unwanted redeposition
.