M. Kobayashi et al., IMPROVEMENT IN TRANSMITTANCE AND DECAY TIME OF PBWO4 SCINTILLATING CRYSTALS BY LA-DOPING, Nuclear instruments & methods in physics research. Section A, Accelerators, spectrometers, detectors and associated equipment, 399(2-3), 1997, pp. 261-268
The optical transparency of PbWO4 single crystals in the short wavelen
gth region between 320 nm (cutoff) and 450 nm is significantly improve
d by doping with a small amount of La. This result indicates the possi
bility that the light yield detected by photomultipliers in actual det
ectors could be significantly increased for the fast blue emission whi
ch peaks around 420 nm. The improvement in transmittance was compared
for different amounts of La doping. La-doping also shortens the decay
time; the best fit of the decay spectrum is a sum of three exponential
s for undoped PbWO4, while it is a sum of two exponentials for La-dope
d PbWO4 with the absence of the next to the fastest component. GDMS an
alysis was carried out for the grown crystals to evaluate any other im
purities.