SYNTHESIS OF 2-PHENYLPERFLUOROPROPENE AND 1,1,1,3,3,3-HEXAFLUORO-2-PHENYLPROPANE

Authors
BHADURY PS PANT BP PALIT M JAISWAL DK
Citation
Ps. Bhadury et al., SYNTHESIS OF 2-PHENYLPERFLUOROPROPENE AND 1,1,1,3,3,3-HEXAFLUORO-2-PHENYLPROPANE, Journal of fluorine chemistry, 85(2), 1997, pp. 115-116
Citations number
9
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of fluorine chemistry → ACNP
ISSN journal
00221139
Volume
85
Issue
2
Year of publication
1997
Pages
115 - 116
Database
ISI
SICI code
0022-1139(1997)85:2<115:SO2A1>2.0.ZU;2-K
Abstract
We describe the optimisation of reaction conditions for the synthesis of 2-phenylperfluoropropene and its HF addition product 1,1,1,3,3,3-he xafluoro-2-phenylpropane from 1,1,1-trifluoroacetophenone by the react ion with sodium chlorodifluoroacetate and triphenylphosphine in dimeth ylformamide. The formation of olefin and the addition product has been studied over a range of temperature (50-150 degrees C) as a function of time. (C) 1997 Elsevier Science S.A.