REACTIONS OF TRIFLUOROVINYLLITHIUM AND 1-CHLORO-2,2-DIFLUOROVINYLLITHIUM - THE SYNTHESIS OF FLUORINATED HETEROCYCLES

Authors
BURDON J COE PL HASLOCK IB POWELL RL
Citation
J. Burdon et al., REACTIONS OF TRIFLUOROVINYLLITHIUM AND 1-CHLORO-2,2-DIFLUOROVINYLLITHIUM - THE SYNTHESIS OF FLUORINATED HETEROCYCLES, Journal of fluorine chemistry, 85(2), 1997, pp. 151-153
Citations number
6
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of fluorine chemistry → ACNP
ISSN journal
00221139
Volume
85
Issue
2
Year of publication
1997
Pages
151 - 153
Database
ISI
SICI code
0022-1139(1997)85:2<151:ROTA1>2.0.ZU;2-O
Abstract
Trifluorovinyllithium (from 1,1,1,2-tetrafluoroethane [HFC-134a]) reac ted with 2-trifluoromethylaniline at -78 degrees C to give 1,2,3-trifl uoroquinoline in moderate to good yield. In a similar reaction, 1-chlo rodifluorovinyllithium (from 1-chloro-2,2,2-trifluoroethane [HCFC-133a ]) yielded 2-chloro-1,3-difluoroquinoline. (C) 1997 Elsevier Science S .A.