ABOUT ALKALI SELENO BISMUTHATES (III), WI TH A COMMENT REGARDING THE TH3P4 STRUCTURE TYPE

Authors
BRONGER W DONIKE A SCHMITZ D
Citation
W. Bronger et al., ABOUT ALKALI SELENO BISMUTHATES (III), WI TH A COMMENT REGARDING THE TH3P4 STRUCTURE TYPE, Zeitschrift fur anorganische und allgemeine Chemie, 623(11), 1997, pp. 1715-1718
Citations number
9
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur anorganische und allgemeine Chemie
ISSN journal
00442313 → ACNP
Volume
623
Issue
11
Year of publication
1997
Pages
1715 - 1718
Database
ISI
SICI code
0044-2313(1997)623:11<1715:AASB(W>2.0.ZU;2-8
Abstract
The synthesis and X-ray single crystal structure determination of the ternary selenides Rb3BiSe3, Cs3BiSe3, and RbK2BiSe3 are described. The compounds were synthesized via a reaction of Bi2O3 with the alkali ca rbonate in a selen-charged hydrogen stream at 850 degrees C. They crys tallize in the Na3AsS3 structure type (space group P2(1)3). In the dis cussion of the structure, the aristotypic Th3P4 structure is included.