WAVE-FUNCTION SPLITTING TECHNIQUE FOR CALCULATING ABOVE-THRESHOLD IONIZATION ELECTRON-SPECTRA

Citation
S. Chelkowski et Ad. Bandrauk, WAVE-FUNCTION SPLITTING TECHNIQUE FOR CALCULATING ABOVE-THRESHOLD IONIZATION ELECTRON-SPECTRA, International journal of quantum chemistry, 60(7), 1996, pp. 473-477
Citations number
10
Categorie Soggetti
Chemistry Physical
ISSN journal
00207608
Volume
60
Issue
7
Year of publication
1996
Pages
473 - 477
Database
ISI
SICI code
0020-7608(1996)60:7<473:WSTFCA>2.0.ZU;2-L
Abstract
In intense laser fields, atoms and molecules can absorb many more phot ons than required for ionization. This phenomenon is called above-thre shold ionization (ATI) and it shows up in kinetic energy spectra of io nized electrons. The presence of very high energy photoelectrons neces sitates the use of extremely large grids in numerical simulations base d on the full time-dependent Schrodinger equation. We show that by usi ng a wave function splitting scheme one can circumvent the problem of large grids and thus obtain accurate multiphoton photoelectron spectra . This scheme will be very useful in studies of ATI spectra generated by molecules in intense laser fields. We illustrate this method for a one-dimensional model of the H atom in intense laser fields. (C) 1996 John Wiley & Sons, Inc.