We have carried out maps of microwave lines of 8 different molecules (
(CO)-C-12(2-1 and 1-0), (CO)-C-13(2-1 and 1-0), SiO(5-4), HCO+(1-0), S
O2(10(0),(10)-9(1,9)), CS(5-4), HCN(1-0) and HNC(1-0)) in OH 231.8+4.2
, a protoplanetary nebula that shows a particularly rich molecular emi
ssion. Confirming previous observations, the total molecular extent is
comparable to the optical image and the lines show a total velocity r
ange similar to [-80:+250] km s(-1) (LSR), due to a high-velocity flow
in the axial direction. The observed transitions show a practically c
onstant velocity gradient, similar to 6 km s(-1) per arcsec, in the di
rection of the polar axis. All the observed molecular lines (except fo
r HCO+) show similar emission features: an intense component in the ve
locity range [+10:+55] that comes from the nebula center, and weaker w
ing emission originating in the lobes, that appear fragmented in sever
al gas components flowing at high velocity in the axial direction. HCO
+, remarkably, does not show a dominant central feature, its emission
being dominated by the contribution of the fast clumps. From the inten
sity ratio of the (CO)-C-13 transitions, we have estimated that the CO
excitation remains practically constant in the whole nebula, the rota
tional temperature showing a low value, similar to 10 K. We have also
calculated the mass, momentum and molecular abundances in the differen
t components of the nebula. We estimate a total molecular mass in the
envelope of 0.5-1 M., and at least 0.2 M. are axially flowing at veloc
ities (with respect to the systemic one) larger than 40 km s(-1). It i
s argued that this material corresponds to a large fraction of the env
elope ejected in the previous AGE phase, after being accelerated by in
teraction with the fast post-AGE jets. We stress that the high value o
f the measured axial momentum cannot be explained by radiation pressur
e, a different mechanism for the release of kinetic momentum by the st
ar must be at work. The abundances of CS, HNC and HCN are found to be
practically constant across the nebula. SO2 is more abundant in the so
uth lobe, while SiO shows the opposite behavior, confirming the asymme
try of the source with respect to the equatorial plane. The HCO+ abund
ance is found to be much higher in the axial flow than in the central
component of the nebula, as expected in view of its intensity distribu
tion. We suggest that this molecule (and probably SiO) is efficiently
formed in the lobes of OH 231.8+4.2 by shock-induced reactions.