Communication: In lithographic techniques for forming nanostructures i
n surfaces and polymer thin films, the selectivity of the solvent beco
mes increasingly important as the target dimensions decrease. Polymer-
based resist systems are reported that use supercritical (SC) CO2 inst
ead of water-based developers. The Figure shows the SC CO2-developed i
mage of a copolymer of pentafluoropropyl methacrylate and tert-butyl m
ethacrylate.