The influence of laser-induced two-electron excitation processes on th
e deflection of atoms by a standing-wave laser field is investigated.
In particular, isolated-core excitation processes are studied in which
, after preparing one valence electron as an electronic Rydberg wave p
acket, the core electron is driven resonantly by the standing wave. Th
e dynamics of the two electrons are entangled through laser-induced el
ectron correlation effects. A theoretical approach is developed that c
learly exhibits the intricate interplay between these correlation effe
cts and the atomic center-of-mass motion that originates from the stim
ulated light force. Various examples are analyzed that show the manife
stations of this interplay in the diffraction pattern of a deflected a
tom.