S. Dangel et R. Holzner, SEMICLASSICAL THEORY FOR THE INTERACTION DYNAMICS OF LASER-LIGHT AND SODIUM ATOMS INCLUDING THE HYPERFINE-STRUCTURE, Physical review. A, 56(5), 1997, pp. 3937-3949
The conventional J = 1/2<->J = 1/2 model is successful for the qualita
tive description of the interaction of sodium atoms and laser light tu
ned close to the atomic D-1 transition. However, time constants for dy
namic effects due to optical pumping predicted by the model are about
an order of magnitude too short compared to experimental observations.
The inclusion of hyperfine states in the quantum-mechanical descripti
on of the atom leads to a satisfactory model that also predicts the co
rrect absorption due to atomic diffusion and allows for the descriptio
n of effects related to population trapping. This hyperfine model is d
erived in detail and compared with the J = 1/2<->J=1/2 approximation.
[S1050-2947(97)00911-6].