ISOLATION OF A REMARKABLY STABLE HYDROGEN-BONDED DIMERIC MANGANESE(II) COMPLEX, [MN(L)(OH2)](2)(ME(2)SO)(2) FROM THE REDUCTION OF A MANGANESE(III) SCHIFF-BASE COMPLEX [L=THE DIANION OF 5-NITROSALICYLIDENE)-1,2-DIAMINO-(2-METHYL)ETHANE]

Authors
BERMEJO MR GARCIADEIBE A SANMARTIN J SOUSA A AURANGZEB N HULME CE MCAULIFFE CA PRITCHARD RG WATKINSON M
Citation
Mr. Bermejo et al., ISOLATION OF A REMARKABLY STABLE HYDROGEN-BONDED DIMERIC MANGANESE(II) COMPLEX, [MN(L)(OH2)](2)(ME(2)SO)(2) FROM THE REDUCTION OF A MANGANESE(III) SCHIFF-BASE COMPLEX [L=THE DIANION OF 5-NITROSALICYLIDENE)-1,2-DIAMINO-(2-METHYL)ETHANE], Journal of the Chemical Society, Chemical Communications, (5), 1994, pp. 645-646
Citations number
29
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
5
Year of publication
1994
Pages
645 - 646
Database
ISI
SICI code
0022-4936(1994):5<645:IOARSH>2.0.ZU;2-H
Abstract
The crystal structure of [Mn(L)(OH2)](2)(Me(2)SO)(2) [L = the dianion of 5-nitrosalicylidene)-1,2-diamino-(2-methyl)ethane] shows it to be a strongly hydrogen-bonded dimer of manganese(II), produced by recrysta llisation of a manganese(III) Schiff base acetate complex from dimethy l sulfoxide.