PALLADIUM-CATALYZED [3- OBSERVATION OF THE ROOM-TEMPERATURE FLUORESCENCE-SPECTRUM OF THE TMM-C-60 ADDUCT(2] CYCLOADDITION OF TRIMETHYLENEMETHANE (TMM) AND FULLERENE )

Authors
SHIU LL LIN TI PENG SM HER GR JU DD LIN SK HWANG JH MON CY LUH TY
Citation
Ll. Shiu et al., PALLADIUM-CATALYZED [3- OBSERVATION OF THE ROOM-TEMPERATURE FLUORESCENCE-SPECTRUM OF THE TMM-C-60 ADDUCT(2] CYCLOADDITION OF TRIMETHYLENEMETHANE (TMM) AND FULLERENE ), Journal of the Chemical Society, Chemical Communications, (5), 1994, pp. 647-648
Citations number
42
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
5
Year of publication
1994
Pages
647 - 648
Database
ISI
SICI code
0022-4936(1994):5<647:P[OOTR>2.0.ZU;2-7
Abstract
The first synthesis of the parent TMM-C-60 adduct 1 was achieved by me ans of Pd-o-mediated [3 + 2] cycloaddition and its structure was unamb iguously proved by spectroscopic means (H-1 and C-13 NMR and MS); a pe ntane solution of the adduct 1 exhibited a fluorescence emission spect rum with lambda(max) 704 nm and vibronic fine structure at ambient tem perature.