RAMAN-SPECTRA AND CONFORMATIONAL-ANALYSIS OF LONG-METHYLENE-CHAIN-DIAMINE-COPPER COMPLEXES

Authors
ANASTASSOPOULOU JD BERJOT M MARX J PALEOS CM THEOPHANIDES T ALIX AJP
Citation
Jd. Anastassopoulou et al., RAMAN-SPECTRA AND CONFORMATIONAL-ANALYSIS OF LONG-METHYLENE-CHAIN-DIAMINE-COPPER COMPLEXES, Journal of molecular structure, 415(3), 1997, pp. 225-237
Citations number
15
Categorie Soggetti
Chemistry Physical
Journal title
Journal of molecular structure → ACNP
ISSN journal
00222860
Volume
415
Issue
3
Year of publication
1997
Pages
225 - 237
Database
ISI
SICI code
0022-2860(1997)415:3<225:RACOL>2.0.ZU;2-K
Abstract
Solid powders of long methylene chain diamines NH2-(CH2)(n)-NH2 with n = 10, 12, and their newly synthesized copper complexes were studied b y laser visible Raman spectroscopy. In this study, we mainly focus on the intensity variations of both the symmetrical and anti-symmetrical stretching vibrational modes of the CH2 groups situated in the high-fr equency range 2800-3000 cm(-1) and on the skeletal vibrations (C-C bon ding) in the region 1050-1150 cm(-1), which shows an unusual behaviour upon complexation of the diamines with the copper ion. (C) 1997 Elsev ier Science B.V.