With the use of scanning tunneling microscopy, it is shown that german
ium atoms adsorbed on the (100) surface of silicon near room temperatu
re form chainlike structures that are tilted from the substrate dimer
bond direction and that consist of two-atom units arranged in adjoinin
g substrate troughs, These units are distinctly different from surface
dimers. They may provide the link missing in our understanding of the
elementary processes in epitaxial film growth: the step between monom
er adsorption and the initial formation of two-dimensional growth isla
nds.