THE CAPACITY DETERIORATION MODEL OF MECHANICALLY ALLOYED MGXNI100-X AMORPHOUS ELECTRODES IN CHARGING-DISCHARGING CYCLING

Citation
Wh. Liu et al., THE CAPACITY DETERIORATION MODEL OF MECHANICALLY ALLOYED MGXNI100-X AMORPHOUS ELECTRODES IN CHARGING-DISCHARGING CYCLING, International journal of hydrogen energy, 22(10-11), 1997, pp. 999-1003
Citations number
15
Categorie Soggetti
Energy & Fuels","Environmental Sciences","Physics, Atomic, Molecular & Chemical
ISSN journal
03603199
Volume
22
Issue
10-11
Year of publication
1997
Pages
999 - 1003
Database
ISI
SICI code
0360-3199(1997)22:10-11<999:TCDMOM>2.0.ZU;2-P
Abstract
In this paper, a relationship between the electrochemical capacity of mechanically alloyed MgXNi100-X amorphous hydride electrodes and disch arging time is deduced on the basis of oxidation of Mg and Ni. The exp erimental data are in good agreement with the deduced relation. Analys is shown that this is the common mechanism of hydride electrode degrad ation when the activation process is ignored. The parameters m and B o f some amorphous hydrides art calculated on the basis of this relation . (C) 1997 International Association for Hydrogen Energy.