SYNTHESIS AND CHARACTERIZATION OF A NEW VANADIUM-OXIDE, TMAV(8)O(20)

Authors
CHIRAYIL T ZAVALIJ PY WHITTINGHAM MS
Citation
T. Chirayil et al., SYNTHESIS AND CHARACTERIZATION OF A NEW VANADIUM-OXIDE, TMAV(8)O(20), Journal of materials chemistry, 7(11), 1997, pp. 2193-2195
Citations number
27
Categorie Soggetti
Chemistry Physical","Material Science
Journal title
Journal of materials chemistry → ACNP
ISSN journal
09599428
Volume
7
Issue
11
Year of publication
1997
Pages
2193 - 2195
Database
ISI
SICI code
0959-9428(1997)7:11<2193:SACOAN>2.0.ZU;2-3
Abstract
Hydrothermal synthesis of V2O5 + TMA + LIOH in a 1:2:1 molar ratio aft er adjusting the pH with acetic acid to pH 3.3 resulted in the formati on of a new vanadium oxide, TMAV(8)O(20). The new vanadium oxide has a monoclinic structure with space group C2/m and lattice parameters: a = 23.655(2), b = 3.5931(3), c = 6.3175(5) Angstrom and beta = 103.060( 4)degrees. TMAV(8)O(20) has a layered structure with the vanadium atom in the octahedral sites and tetramethylammonium ions residing in betw een the vanadium layers.