B. Jamtveit et al., HIGH-GRADE CONTACT-METAMORPHISM OF CALCAREOUS ROCKS FROM THE OSLO RIFT, SOUTHERN NORWAY, The American mineralogist, 82(11-12), 1997, pp. 1241-1254
Shallow-level plutons caused extensive contact metamorphism of Lower P
aleozoic shale and carbonate sequences in the Permian Oslo Rift. A >50
0 m long and 100 m wide shale-limestone xenolith embedded within monzo
nites belonging to the Skrim plutonic complex experienced high-grade c
ontact metamorphism and generation of minerals and mineral assemblages
rarely reported from metamorphic rocks. The peak metamorphic (Stage I
) assemblages in calcite-saturated rocks include wollastonite, melilit
es, fassaitic pyroxenes, phlogopite, titanian grossular, kalsilite, ne
pheline, perovskite, cuspidine, baghdadite, pyrrhotite, and occasional
graphite. Mineral reactions involving detrital apatite produced a ser
ies of silicate apatites, including the new mineral species Ca-3.5(Th,
U)(1.5)Si3O12 (OH). This assemblage equilibrated at T = 820-870 degree
s C with a C-rich, internally buffered pore-fluid (20-40 mol% CO2 + CH
4). During cooling the shale-limestone xenolith experienced infiltrati
on of C-poor (< 0.1 mol% CO2) fluids, triggering the formation of retr
ograde (Stage II) mineral assemblages comprising monticellite, tilleyi
te, vesuvianite, grandite garnets, diopside, and occasional hillebrand
ite. Rare potassium iron sulfides (rasvumite and djerfisherite) formed
at the expense of primary pyrrhotite. These assemblages probably form
ed near 700 degrees C. Formation of diffuse sodalite-bearing veinlets
was associated with breakdown of nepheline and the replacement of kals
ilite and wollastonite by potassium feldspar. The sodalite-bearing Sta
ge III assemblage formed by the infiltration of saline brines at a max
imum temperature of 550 degrees C. Low-temperature (Stage IV) retrogre
ssion of the Stage I-m assemblage produced scawtite, giuseppettite, hy
drogrossulars, phillipsite, thomsonite, and three hitherto undescribed
mineral species.