A new method for studying of vibronic transitions by scanning tunnelin
g microscope (''intraresonator electron-vibronic scanning tunneling sp
ectroscopy of adsorbates'') is proposed. Results of experiments carrie
d out by STM ''Omicron'' where electron-vibronic series of field emiss
ion resonances were observed are presented. Frequencies of the resonan
ces correspond to ones of local vibrations of titan oxide and adsorbed
hydroxil particles.