SYNTHESIS AND PROPERTIES OF A SERIES OF NEW ASYMMETRICAL TETRATHIAFULVALENE DERIVATIVES

Authors
LI HQ YAO ZQ LIU D TAN GZ YU XD
Citation
Hq. Li et al., SYNTHESIS AND PROPERTIES OF A SERIES OF NEW ASYMMETRICAL TETRATHIAFULVALENE DERIVATIVES, Synthetic metals, 90(1), 1997, pp. 49-55
Citations number
34
Categorie Soggetti
Physics, Condensed Matter","Material Science","Polymer Sciences
Journal title
Synthetic metals → ACNP
ISSN journal
03796779
Volume
90
Issue
1
Year of publication
1997
Pages
49 - 55
Database
ISI
SICI code
0379-6779(1997)90:1<49:SAPOAS>2.0.ZU;2-B
Abstract
A series of new asymmetrically substituted tetrathiafulvalene (TTF) de rivatives, a charge transfer (CT) complex, and several related symmetr ical TTF derivatives were synthesized. The compounds were characterize d by elemental analysis, H-1 NMR spectra, LR spectra, and electron ion ization (EI) or negative-ion fast atom bombardment (FAB) mass spectral analysis. UV-Vis spectra of the new asymmetrical TTF derivatives and the CT complex in solution were investigated. In addition, mixed condu cting Langmuir-Blodgett (LB) films were constructed from the asymmetri cal TTF derivatives by admiring with an equimolar arachidic acid. (C) 1997 Elsevier Science S.A.