ELABORATION OF S-(-)-ALPHA-PINENE INTO FUNCTIONALIZED BICYCLO[4.2.1]NONANE FRAMEWORK OF MEDITERRANEOLS

Authors
MEHTA G ACHARYULU PVR REDDY KS UMARYE JD
Citation
G. Mehta et al., ELABORATION OF S-(-)-ALPHA-PINENE INTO FUNCTIONALIZED BICYCLO[4.2.1]NONANE FRAMEWORK OF MEDITERRANEOLS, Synlett, (10), 1997, pp. 1161
Citations number
12
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synlett → ACNP
ISSN journal
09365214
Issue
10
Year of publication
1997
Database
ISI
SICI code
0936-5214(1997):10<1161:EOSIFB>2.0.ZU;2-Q
Abstract
A two-carbon ring expansion of (-)-alpha-pinene 1 to bicyclo[5.1.1]non ane system (+)-12 and 1,2-cationic rearrangement provides an entry int o a functionalized bicyclo[4.2.1]nonane derivative, representing the c arbocyclic skeleton, present in the novel marine diterpenes, mediterra neols.