DIRHODIUM(II) TETRAACETATE-MEDIATED DECOMPOSITION OF ETHYLDIAZOACETATE AND ETHYLDIAZOMALONATE IN THE PRESENCE OF FULLERENE - A NEW PROCEDURE FOR THE SELECTIVE SYNTHESIS OF [6-6]-CLOSED METHANOFULLERENES

Authors
PELLICCIARI R ANNIBALI D COSTANTINO G MARINOZZI M NATALINI B
Citation
R. Pellicciari et al., DIRHODIUM(II) TETRAACETATE-MEDIATED DECOMPOSITION OF ETHYLDIAZOACETATE AND ETHYLDIAZOMALONATE IN THE PRESENCE OF FULLERENE - A NEW PROCEDURE FOR THE SELECTIVE SYNTHESIS OF [6-6]-CLOSED METHANOFULLERENES, Synlett, (10), 1997, pp. 1196
Citations number
21
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synlett → ACNP
ISSN journal
09365214
Issue
10
Year of publication
1997
Database
ISI
SICI code
0936-5214(1997):10<1196:DTDOE>2.0.ZU;2-L
Abstract
The reaction of C-60 fullerene with carboalkoxycarbenoids generated by Rh-2(OAc)(4)-catalyzed decomposition of alpha-diazoester precursors i s reported. This reaction is the first example of a transition metal c atalyzed carbenoid reaction with fullerene and represents a significat ive improvement in terms of reaction conditions, selectivity of the pr oducts obtained, and yields over previously reported methods.