FERROCENYLDIHALOPHOSPHANES

Citation
R. Pietschnig et E. Niecke, FERROCENYLDIHALOPHOSPHANES, Bulletin de la Societe chimique de France, 134(6), 1997, pp. 605-608
Citations number
19
Categorie Soggetti
Chemistry Inorganic & Nuclear",Biology,Chemistry
ISSN journal
00378968
Volume
134
Issue
6
Year of publication
1997
Pages
605 - 608
Database
ISI
SICI code
0037-8968(1997)134:6<605:F>2.0.ZU;2-Q
Abstract
An improved synthesis for ferrocenyldichlorophosphane, FcPCl(2) (Fc = C5H4FeC5H5) is reported. The availability of this compound gives acces s to the other, previously unknown members of the homologous ferroceny ldihalophosphane series, FcPX(2) (X = F, Br, I). The latter are charac terised by NMR and high-resolution mass spectroscopy. The class of fer rocenyldihalophosphanes is a valuable synthon for the generation of a large variety of ferrocenylphosphanes.