Aggregates of particles formed in coagutation/flocculation processes v
ery often have a fractal, self-similar structure, with the very import
ant practical consequence that the effective density of aggregates dec
reases as their size increases. This has very significant effects on s
eparation processes such as sedimentation, notation and filtration. Th
e fundamental factors which influence the density of aggregates (flocs
) are reviewed, with a discussion of the effects on aggregate size dis
tribution, the rate of formation of flocs and their capture by collect
ors. Several experimental methods for determining flee density are cri
tically examined. (C) 1997 IAWQ. Published by Elsevier Science Ltd.