CONTROLLING ELECTROCHEMICAL CHAOS IN THE COPPER-PHOSPHORIC ACID SYSTEM

Citation
Iz. Kiss et al., CONTROLLING ELECTROCHEMICAL CHAOS IN THE COPPER-PHOSPHORIC ACID SYSTEM, The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory, 101(46), 1997, pp. 8668-8674
Citations number
21
Categorie Soggetti
Chemistry Physical
ISSN journal
10895639
Volume
101
Issue
46
Year of publication
1997
Pages
8668 - 8674
Database
ISI
SICI code
1089-5639(1997)101:46<8668:CECITC>2.0.ZU;2-Z
Abstract
Model calculations indicate that chaotic current oscillations during a nodic electrodissolution of copper into phosphoric acid may be control led by applying a simple map-based algorithm. In the experiments, the unstable period-one and period-two orbits embedded in the chaotic attr actor have been stabilized by small perturbations of the anodic potent ial. We present the results of an experimental test for a power law re lating the average chaotic transient time to the size of maximum pertu rbation allowed during control. The reported experimental results are in good agreement with the theoretical predictions by Ott, Grebogi, an d Yorke.