COLLOIDAL PROCESSING AND MECHANICAL-PROPERTIES OF SILICON-CARBIDE WITH ALUMINA

Submicrometer-sized SiC coated with SiO2 of 0.4-1.8 wt. % and alpha-Al 2O3 powder of median size 0.2 mu m were mixed in aqueous solutions in the pH range 3.0-10.0, The SiC/Al2O3 (4.3-6.9 wt. %) powders were cons olidated by filtration through gypsum molds and hot-pressed at 1600 de grees-2040 degrees C under a pressure of 39 MPa. These compacts were d ensified to near the theoretical density at 1700 degrees-1800 degrees C. The sintering mechanisms are discussed based on the analysis of shr inkage curves of SiC/Al2O3 compacts during hot-pressing, The equiaxed SiC grains grew with low aspect ratios below 1800 degrees C and change d to plate-like grains at 1900 degrees C, The fracture toughness of Si C as a function of average grain size reached a maximum of 5 MPa.m(0.5 ) at 2.5 mu m grains of low aspect ratios of 1-2. The flexural strengt hs at room temperature were 230-430 MPa in the SiC above 98% of the th eoretical density and showed a similar grain size dependence.