PREPARATION AND ELECTRICAL-PROPERTIES OF RADICAL-CATION SALTS BASED ON 1,3-DITHIANE DERIVATIVES

Authors
YAMADA J AKASHI N ANZAI H TAMURA M NISHIO Y KAJITA K
Citation
J. Yamada et al., PREPARATION AND ELECTRICAL-PROPERTIES OF RADICAL-CATION SALTS BASED ON 1,3-DITHIANE DERIVATIVES, Molecular crystals and liquid crystals science and technology. Section A, Molecular crystals and liquid crystals, 296, 1997, pp. 53-59
Citations number
9
Categorie Soggetti
Crystallography
Journal title
Molecular crystals and liquid crystals science and technology. Section A, Molecular crystals and liquid crystals → ACNP
ISSN journal
1058725X
Volume
296
Year of publication
1997
Pages
53 - 59
Database
ISI
SICI code
1058-725X(1997)296:<53:PAEORS>2.0.ZU;2-F
Abstract
Preparation of radical cation salts based on 1,3-dithiane derivatives (1,2 and 5-8) was investigated. Although attempts to prepare stable ra dical cation salts derived from 1 and 2 were unsuccessful, various rad ical cation salts composed of TTF (tetrathiafulvalene) derivatives fus ed with a 2-(1,3-dithiol-2-ylidene)-1,3-dithiane (DTDT) unit (5-8) wer e formed with ease by electrochemical oxidation. Several radical catio n salts of 6-8 exhibited metallic conducting behaviors on a single cry stal or compressed pellets.