Y. Suzuki et al., MANUFACTURING NANO-DIPHASIC MATERIALS FROM NATURAL DOLOMITE - IN-SITUOBSERVATION OF NANOPHASE FORMATION BEHAVIOR, Journal of the American Ceramic Society, 80(11), 1997, pp. 2949-2953
Decomposition of the mixed carbonate mineral dolomite, CaMg(CO3)(2), a
nd formation of CaO/MgO nanopolycrystals were observed in situ using a
field emission scanning electron microscope with a hot stage. The pyr
olysis behavior of dolomite was studied with an in situ high-temperatu
re X-ray powder diffraction technique. Nano-sized particles formed dur
ing pyrolysis then sintered into CaO/MgO nanopolycrystals. Dense bulk-
form CaO/MgO and CaZrO3/MgO nanocomposites were successfully fabricate
d using reactive hot-pressing from dolomite and dolomite/zirconia mixe
d powders, respectively.