The Earth's physical properties show a dominantly radial structure whi
ch is the result of compositional differentiation, isochemical phase c
hanges(1) and rheological layering(2). Rheological layering is perhaps
the most difficult to investigate using conventional seismological te
chniques because the seismic manifestation of this property, elastic a
nisotropy, may closely mimic the effects of isotropic heterogeneity(3)
. Nonetheless, an improved characterization of Earth's rheological str
ucture promises important insights into such processes as plate dynami
cs and continental evolution. Here, I present a methodology for effect
ively characterizing sharp transitions in anisotropic, upper-mantle st
ructure using the coda of teleseismic P-waves. Application to seismogr
ams from the Slave craton reveals a well-developed stratigraphy, at le
ast in part anisotropic, with major boundaries occurring at nominal de
pths of 75, 135 and 195 km. The geometry and sharpness of these discon
tinuities suggest a structural origin, perhaps involving shallow subdu
ction.