Nuclear spin relaxation experiments with Li-8 adsorbed on various surf
aces provide new information in surface science which is not obtainabl
e othervise. Both dipolar (Korringa) and quadrupolar relaxation due to
diffusion are observed. However, in addition, a fast and presently no
t understood spin relaxation mechanism is present while dosing during
the first 0.5 s the surface with polarized Li-8. Most strange in this
respect is the fact that those Li-8 atoms which survive depolarization
through this mechanism depolarize afterwards with modest spin lattice
relaxation rates. The origin of the fast spin lattice relaxation mech
anism is presently unknown.