A suite of oils from stacked reservoirs in the Unity Field in Sudan ha
s been analyzed by various geochemical techniques for molecular inform
ation to elucidate the geological processes which cause variations in
oil composition and their resulting oil fingerprints in different rese
rvoir units. Analyses of these highly paraffinic oils indicate that th
e chromatographic fingerprint variations are due to differences in the
abundances of saturated compounds, including branched and cyclic alka
nes. Neither aromatics nor NSO compounds have any significant effect o
n the observed fingerprint variations. This association of saturates,
instead of aromatics and NSO compounds. with the fingerprint variation
s precludes rock fluid interactions as a cause of the variations. Biom
arker analyses show that variations in thermal maturity and organic fa
cies of the source rock are responsible for the fingerprint variations
. Thermal maturity increases with the depth of the reservoir, suggesti
ng a multiple-charge process for the oils to fill these reservoirs ove
r an extended period of time. Apparently the source rock generated and
expelled progressively more mature oils and little mixing occurred du
ring migration. Thus, knowledge of oil compositional variations from o
ne reservoir to another, organic facies variation and source rock matu
rity combined with tectonic history may help explain charging and timi
ng of oil emplacement.